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In firefox it's in the settings:http://i.imgur.com/WlAvCys.pngsearch for BIN or WORD
It is your Operating System that decides to bind .bin files to word. Also your browser could have an "application" linked to open .bin files directly instead of downloading it. You need to check those bindings!
Are you saying it's saving AS a word document? If so, open in notepad and maybe attempt to save it as a .bin. Or maybe your default program for bins in word. It's unclear what you're asking.